Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

• Main Authors: Guo, Jia-Yi, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2013
• Online Access: https://hdl.handle.net/10356/100998; http://hdl.handle.net/10220/13701
• Institution: Nanyang Technological University

The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯...