Reactivity of a tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide complex toward isocyanates and rhodium(I) chloride

The reaction of the tin(II) (iminophosphinoyl)(thiophosphinoyl)methanediide [(PPh2═NSiMe3)(PPh2═S)CSn:]2 (1) with AdNCO (Ad = adamantyl), ArNCO (Ar = 2,6-Pri2C6H3), and [RhCl(cod)]2 in THF afforded [(PPh2═NSiMe3)(PPh2═S)tiebar above startC{C(O)N(Ad)}tiebar above endSn:] (2), [(PPh2═NSiMe3)(PPh2═S)C¯...

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Bibliographic Details
Main Authors: Guo, Jia-Yi, Li, Yongxin, Ganguly, Rakesh, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/100998
http://hdl.handle.net/10220/13701
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Institution: Nanyang Technological University
Language: English

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