Direct β-activation of saturated aldehydes to formal michael acceptors through oxidative NHC catalysis
Without detours: Oxidative catalysis mediated by N-heterocyclic carbenes (NHCs) enables the direct β-carbon functionalization of saturated aldehydes (see scheme). The reaction proceeds through two sequential oxidative steps to generate ,β-unsaturated triazolium ester equivalents as formal Michael ac...
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| Main Authors: | , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/104151 http://hdl.handle.net/10220/19431 |
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| Institution: | Nanyang Technological University |
| Language: | English |