Direct β-activation of saturated aldehydes to formal michael acceptors through oxidative NHC catalysis

Without detours: Oxidative catalysis mediated by N-heterocyclic carbenes (NHCs) enables the direct β-carbon functionalization of saturated aldehydes (see scheme). The reaction proceeds through two sequential oxidative steps to generate ,β-unsaturated triazolium ester equivalents as formal Michael ac...

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Bibliographic Details
Main Authors: Mo, Junming, Shen, Liang, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2014
Subjects:
Online Access:https://hdl.handle.net/10356/104151
http://hdl.handle.net/10220/19431
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Institution: Nanyang Technological University
Language: English