Ruthenium mimics of [Fe]-hydrogenase: synthesis, reactivity and peptide conjugation

• Main Author: Wong, Zhen Xuan
• Other Authors: Leong Weng Kee
• Format: Final Year Project
• Language: English
• Published: Nanyang Technological University 2023
• Subjects: Science::Chemistry::Inorganic chemistry
• Online Access: https://hdl.handle.net/10356/169669
• Institution: Nanyang Technological University

In this work, further derivatization on the aminopyridyl ring at the 4- or 6-position of the previously reported ruthenium-based structural mimics of the [Fe]-hydrogenase was explored to assess their structural and electronic effects. It was found that there is a substituent effect at the 6-position...