Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles
Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle.
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| Main Authors: | , , |
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| 格式: | Article |
| 語言: | English |
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2017
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| 在線閱讀: | https://hdl.handle.net/10356/84965 http://hdl.handle.net/10220/43605 |
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