New thioether–dithiolate complexes of Cp∗Ir and some reactivity features
The reaction of [Cp∗IrCl2]2 (Cp* = η5 − C5Me5) with the tridentate 3-thiapentane-1,5-dithiolate ligand, S(CH2CH2S−)2 (tpdt), led to the formation of [Cp∗Ir(η3 − tpdt)] (1) in 81% isolated yield. Subsequent reactions of 1 with [Cp∗IrCl2]2 in 2:1 and 1:1 molar equiv ratios resulted in the formation of...
Saved in:
| Main Authors: | , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/98546 http://hdl.handle.net/10220/17150 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |