Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles

Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles

Copper-catalyzed aerobic methyl/methylene oxygenation of substituted indoles and pyrroles was developed using 1,4- diazabicyclo[2.2.2]octane (DABCO) as an additive in dimethyl sulfoxide (DMSO). Similar aerobic catalytic conditions could also be utilized for direct C–H formylation of C(3) on indo...

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Main Authors: Wang, Yi-Feng, Zhang, Feng-Lian, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/98672
http://hdl.handle.net/10220/11888
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-986722020-03-07T12:37:07Z Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles Wang, Yi-Feng Zhang, Feng-Lian Chiba, Shunsuke School of Physical and Mathematical Sciences Copper-catalyzed aerobic methyl/methylene oxygenation of substituted indoles and pyrroles was developed using 1,4- diazabicyclo[2.2.2]octane (DABCO) as an additive in dimethyl sulfoxide (DMSO). Similar aerobic catalytic conditions could also be utilized for direct C–H formylation of C(3) on indoles and C(2) on pyrroles. 2013-07-18T07:08:24Z 2019-12-06T19:58:18Z 2013-07-18T07:08:24Z 2019-12-06T19:58:18Z 2012 2012 Journal Article Wang, Y.-F., Zhang, F.-L., & Chiba, S. (2012). Copper-Catalyzed Aerobic Methyl/Methylene Oxygenation and C-H Formylation with a DABCO-DMSO System for the Synthesis of Carbonyl Indoles and Pyrroles. Synthesis, 44(10), 1526-1534. https://hdl.handle.net/10356/98672 http://hdl.handle.net/10220/11888 10.1055/s-0031-1290815 en Synthesis © 2012 Georg Thieme Verlag Stuttgart · New York.
institution Nanyang Technological University
building NTU Library
country Singapore
collection DR-NTU
language English
description Copper-catalyzed aerobic methyl/methylene oxygenation of substituted indoles and pyrroles was developed using 1,4- diazabicyclo[2.2.2]octane (DABCO) as an additive in dimethyl sulfoxide (DMSO). Similar aerobic catalytic conditions could also be utilized for direct C–H formylation of C(3) on indoles and C(2) on pyrroles.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Wang, Yi-Feng
Zhang, Feng-Lian
Chiba, Shunsuke
format Article
author Wang, Yi-Feng
Zhang, Feng-Lian
Chiba, Shunsuke
spellingShingle Wang, Yi-Feng
Zhang, Feng-Lian
Chiba, Shunsuke
Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
author_sort Wang, Yi-Feng
title Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
title_short Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
title_full Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
title_fullStr Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
title_full_unstemmed Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
title_sort copper-catalyzed aerobic methyl/methylene oxygenation and c-h formylation with a dabco-dmso system for the synthesis of carbonyl indoles and pyrroles
publishDate 2013
url https://hdl.handle.net/10356/98672
http://hdl.handle.net/10220/11888
_version_ 1681035279178137600

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