Copper-catalyzed aerobic methyl/methylene oxygenation and C-H formylation with a DABCO-DMSO system for the synthesis of carbonyl indoles and pyrroles
Copper-catalyzed aerobic methyl/methylene oxygenation of substituted indoles and pyrroles was developed using 1,4- diazabicyclo[2.2.2]octane (DABCO) as an additive in dimethyl sulfoxide (DMSO). Similar aerobic catalytic conditions could also be utilized for direct C–H formylation of C(3) on indo...
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Main Authors: | , , |
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格式: | Article |
語言: | English |
出版: |
2013
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在線閱讀: | https://hdl.handle.net/10356/98672 http://hdl.handle.net/10220/11888 |
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機構: | Nanyang Technological University |
語言: | English |