Syntheses and characterization of homodinuclear manganese and cobalt complexes bridged by a hemiacetal or by an acetato group in a μ-(η2:η1) bridging mode

The complex [Mn2(BPMAPS)(μ-OAc)2(hemi)]PF6 (1), where hemi is the hemiacetal group, methoxy(2-pyridyl)methoxo, was prepared from bis[3-(2-pyridylmethyleneamino)phenyl] sulfone (BPMAPS), 2-pyridinecarbaldehyde, and manganese(II) acetate in methanol. The complexes Mn2(BPMAPS)(μ-OAc)2(μ-1,1-OAc)(η1-OAc...

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Bibliographic Details
Main Authors: Guidote, Armando M, Jr, Ando, Ken-ichi, Kurusu, Yasuhiko, Nagao, Hirotaka, Masuyama, Yoshiro
Format: text
Published: Archīum Ateneo 2001
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Online Access:https://archium.ateneo.edu/chemistry-faculty-pubs/52
https://www.sciencedirect.com/science/article/abs/pii/S0020169301002948?via%3Dihub
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Institution: Ateneo De Manila University

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