Synthesis of unique phosphazane macrocycles via steric activation of C-N bonds
Herein we describe that oxidation reactions of the dimeric cyclophosphazanes, [{P(μ-NR)}2(μ-NR)]2, R = tBu (1), to produce a series of diagonally dioxidized products P4(μ-N tBu)6E2 [E = O (2), S (3), and Se (4)] and tetraoxidized frameworks. The latter display an unexpected C-N bond activation and c...
Saved in:
| Main Authors: | , , , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2020
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/140059 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Institution: | Nanyang Technological University |
| Language: | English |