Synthesis of unique phosphazane macrocycles via steric activation of C-N bonds

Synthesis of unique phosphazane macrocycles via steric activation of C-N bonds

Herein we describe that oxidation reactions of the dimeric cyclophosphazanes, [{P(μ-NR)}2(μ-NR)]2, R = tBu (1), to produce a series of diagonally dioxidized products P4(μ-N tBu)6E2 [E = O (2), S (3), and Se (4)] and tetraoxidized frameworks. The latter display an unexpected C-N bond activation and c...

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書目詳細資料
Main Authors:	Shi, Xiaoyan, Martin, Katherine Ann, Liang, Rong Zheng, Star, Daniel G., Li, Yongxin, Ganguly, Rakesh, Sim, Ying, Tan, Davin, Díaz, Jesús, García, Felipe
其他作者:	School of Physical and Mathematical Sciences
格式:	Article
語言:	English
出版:	2020
主題:	Science::Chemistry Group 16 Compounds Bond Cleavage
在線閱讀:	https://hdl.handle.net/10356/140059
標簽:	添加標簽沒有標簽, 成為第一個標記此記錄!

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