Dearylation of arylphosphine oxides using a sodium hydride–iodide composite

A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.

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Main Authors: Tejo, Ciputra, Pang, Jia Hao, Ong, Derek Yiren, Oi, Miku, Uchiyama, Masanobu, Takita, Ryo, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2019
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Online Access:https://hdl.handle.net/10356/85913
http://hdl.handle.net/10220/48244
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-859132023-02-28T19:33:56Z Dearylation of arylphosphine oxides using a sodium hydride–iodide composite Tejo, Ciputra Pang, Jia Hao Ong, Derek Yiren Oi, Miku Uchiyama, Masanobu Takita, Ryo Chiba, Shunsuke School of Physical and Mathematical Sciences Arylphosphine Oxides Sodium Hydride DRNTU::Science::Chemistry A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion. MOE (Min. of Education, S’pore) Accepted version 2019-05-16T09:14:22Z 2019-12-06T16:12:35Z 2019-05-16T09:14:22Z 2019-12-06T16:12:35Z 2018 Journal Article Tejo, C., Pang, J. H., Ong, D. Y., Oi, M., Uchiyama, M., Takita, R., & Chiba, S. (2018). Dearylation of arylphosphine oxides using a sodium hydride–iodide composite. Chemical Communications, 54(14), 1782-1785. doi:10.1039/C8CC00289D 1359-7345 https://hdl.handle.net/10356/85913 http://hdl.handle.net/10220/48244 10.1039/C8CC00289D en Chemical Communications © 2018 The Author(s). All rights reserved. This paper was published by The Royal Society of Chemistry in Chemical Communications and is made available with permission of The Author(s). 4 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Arylphosphine Oxides
Sodium Hydride
DRNTU::Science::Chemistry
spellingShingle Arylphosphine Oxides
Sodium Hydride
DRNTU::Science::Chemistry
Tejo, Ciputra
Pang, Jia Hao
Ong, Derek Yiren
Oi, Miku
Uchiyama, Masanobu
Takita, Ryo
Chiba, Shunsuke
Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
description A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tejo, Ciputra
Pang, Jia Hao
Ong, Derek Yiren
Oi, Miku
Uchiyama, Masanobu
Takita, Ryo
Chiba, Shunsuke
format Article
author Tejo, Ciputra
Pang, Jia Hao
Ong, Derek Yiren
Oi, Miku
Uchiyama, Masanobu
Takita, Ryo
Chiba, Shunsuke
author_sort Tejo, Ciputra
title Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
title_short Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
title_full Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
title_fullStr Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
title_full_unstemmed Dearylation of arylphosphine oxides using a sodium hydride–iodide composite
title_sort dearylation of arylphosphine oxides using a sodium hydride–iodide composite
publishDate 2019
url https://hdl.handle.net/10356/85913
http://hdl.handle.net/10220/48244
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