Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes
An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives...
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| التنسيق: | مقال |
| اللغة: | English |
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2012
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| الوصول للمادة أونلاين: | https://hdl.handle.net/10356/94637 http://hdl.handle.net/10220/8116 |
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sg-ntu-dr.10356-946372020-03-07T12:31:30Z Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes Zhang, Junmin Tiwari, Bhoopendra Xing, Chong Chen, Xingkuan Chi, Robin Yonggui School of Physical and Mathematical Sciences DRNTU::Science::Mathematics::Applied mathematics An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives the desired products with high enantioselectivity. 2012-05-22T08:43:27Z 2019-12-06T18:59:33Z 2012-05-22T08:43:27Z 2019-12-06T18:59:33Z 2012 2012 Journal Article Zhang, J., Tiwari, B., Xing, C., Chen, X. & Chi, R. Y. (2012). Enantioselective Oxidative Cross-Dehydrogenative Coupling of Tertiary Amines to Aldehydes. Angewandte Chemie International Edition, 51(15), 3649-3652. https://hdl.handle.net/10356/94637 http://hdl.handle.net/10220/8116 10.1002/anie.201109054 165019 en Angewandte chemie international edition © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| institution |
Nanyang Technological University |
| building |
NTU Library |
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Singapore |
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DR-NTU |
| language |
English |
| topic |
DRNTU::Science::Mathematics::Applied mathematics |
| spellingShingle |
DRNTU::Science::Mathematics::Applied mathematics Zhang, Junmin Tiwari, Bhoopendra Xing, Chong Chen, Xingkuan Chi, Robin Yonggui Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| description |
An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives the desired products with high enantioselectivity. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Zhang, Junmin Tiwari, Bhoopendra Xing, Chong Chen, Xingkuan Chi, Robin Yonggui |
| format |
Article |
| author |
Zhang, Junmin Tiwari, Bhoopendra Xing, Chong Chen, Xingkuan Chi, Robin Yonggui |
| author_sort |
Zhang, Junmin |
| title |
Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| title_short |
Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| title_full |
Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| title_fullStr |
Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| title_full_unstemmed |
Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| title_sort |
enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes |
| publishDate |
2012 |
| url |
https://hdl.handle.net/10356/94637 http://hdl.handle.net/10220/8116 |
| _version_ |
1681042340231249920 |