Abnormal N-heterocyclic carbene gold(I) complexes : synthesis, structure, and catalysis in hydration of alkynes
Two abnormal N-heterocyclic carbene (aNHC) gold(I) complexes, [(aNHC)AuCl], were prepared from C2-protected imidazolium salts. The air-stable complexes chloro(1-isopropyl-3-methyl-2,4-diphenylimidazol-5-ylidene)gold(I) (5) and chloro(1,4-diisopropyl-3-methyl-2-phenylimidazol-5-ylidene)gold(I) (6) we...
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Main Authors: | Xu, Xiangya, Kim, Seung Hyo, Zhang, Xi, Das, Atanu Kumar, Hirao, Hajime, Hong, Soon Hyeok |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2013
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/107225 http://hdl.handle.net/10220/17910 http://dx.doi.org/10.1021/om3009603 |
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Institution: | Nanyang Technological University |
Language: | English |
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