Diverse bonding activations in the reactivity of a pentaphenylborole toward sodium phosphaethynolate : heterocycle synthesis and mechanistic studies
The reaction of the pentaphenylborole [(PhC)4BPh] (1) with sodium phosphaethynolate·1,4-dioxane (NaOCP(1,4-dioxane)1.7) afforded the novel sodium salt of phosphaboraheterocycle 2. It comprises anionic fused tetracyclic P/B-heterocycles that arise from multiple bond activation between the borole back...
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Main Authors: | Li, Yan, Siwatch, Rahul Kumar, Mondal, Totan, Li, Yongxin, Ganguly, Rakesh, Koley, Debasis, So, Cheuk-Wai |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2020
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/139442 |
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Institution: | Nanyang Technological University |
Language: | English |
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