Diastereoselective hydroalkylation of aryl alkenes enabled by remote hydride transfer
Leveraging of 1,5-hydride shift enabled diastereoselective hydroalkylation of aryl alkenes, allowing for construction of consecutive vicinal stereogenic centers in a single process. The transformation is triggered by electrophilic alkylation of aryl alkenes with in-situ generated carbocations, that...
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Main Authors: | Gandamana, Dhika Aditya, Gagosz, Fabien, Chiba, Shunsuke |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2021
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/154141 |
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Institution: | Nanyang Technological University |
Language: | English |
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