Prediction of NHC-catalyzed chemoselective functionalizations of carbonyl compounds : a general mechanistic map
Generally, N-heterocyclic carbene (NHC) complexed with carbonyl compounds would transform into several important active intermediates, i.e., enolates, Breslow intermediates, or acylazolium intermediates, which act as either a nucleophile (Nu) or an electrophile (E) to react with the other E/Nu partn...
Saved in:
Main Authors: | Li, Xue, Xu, Jun, Li, Shi-Jun, Qu, Ling-Bo, Li, Zhongjun, Chi, Robin Yonggui, Wei, Donghui, Lan, Yu |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2022
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/155112 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
Similar Items
-
NHC-catalyzed chemoselective reactions of enals and aminobenzaldehydes for access to chiral dihydroquinolines
by: Wu, Shuquan, et al.
Published: (2020) -
NHC‐catalyzed chemoselective reactions of enals and aminobenzaldehydes for access to chiral dihydroquinolines
by: Wu, Shuquan, et al.
Published: (2023) -
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
by: Lee, Jiawen
Published: (2020) -
NHC-catalyzed enantioselective access to β-cyano carboxylic esters via in situ substrate alternation and release
by: Wang, Qingyun, et al.
Published: (2023) -
Catalytic, enantioselective, and highly chemoselective bromocyclization of olefinic dicarbonyl compounds
by: Zhao, Y., et al.
Published: (2014)