Nickel-catalyzed conjugate addition of alkynyl groups to. alpha.,. beta.-unsaturated ketones
The complex formed by reaction of Ni (acac) 2 and DiBAH (1: 1) catalyzesconjugate addition of dialkylaluminum acetylides to, ß enones;; on hydrolysis, 3-alkynyl ketones are produced in high yield. Through this procedureconjugate addition of alkynyl groups to either S-cis or S-trans enones can be eff...
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| Main Authors: | , , , |
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| Format: | text |
| Published: |
Archīum Ateneo
1980
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| Subjects: | |
| Online Access: | https://archium.ateneo.edu/chemistry-faculty-pubs/96 https://pubs.acs.org/doi/pdf/10.1021/jo01303a024 |
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| Institution: | Ateneo De Manila University |