Asymmetric domino heck arylation and alkylation of nonconjugated dienes : double C–F···sodium attractive noncovalent interaction
Palladium catalyzes a domino Heck arylation and alkylation of nonconjugated cyclodienes to produce trans isomers of disubstituted cyclohexenes in exceptionally high enantiomeric ratios, reaching 100:1 to 200:1 in many cases. Importantly, the interactions of the two CF bonds of Josiphos and the sodiu...
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Main Authors: | Zhu, Daoyong, Xu, Wenqiang, Pu, Maoping, Wu, Yun-Dong, Chi, Robin Yonggui, Zhou, Steve Jianrong |
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其他作者: | School of Physical and Mathematical Sciences |
格式: | Article |
語言: | English |
出版: |
2022
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主題: | |
在線閱讀: | https://hdl.handle.net/10356/155069 |
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機構: | Nanyang Technological University |
語言: | English |
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