Atroposelective access to 1,3-oxazepine-containing bridged biaryls via carbene-catalyzed desymmetrization of imines
We disclose herein an atroposelective synthesis of novel bridged biaryls containing medium-sized rings via N-heterocyclic carbene organocatalysis. The reaction starts with addition of the carbene catalyst to the aminophenol-derived aldimine substrate. Subsequent oxidation and intramolecular desymmet...
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Main Authors: | Yang, Xing, Wei, Liwen, Wu, Yuelin, Zhou, Liejin, Zhang, Xinglong, Chi, Robin Yonggui |
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其他作者: | School of Physical and Mathematical Sciences |
格式: | Article |
語言: | English |
出版: |
2023
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主題: | |
在線閱讀: | https://hdl.handle.net/10356/166232 |
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機構: | Nanyang Technological University |
語言: | English |
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