Cyclisation reactions for the synthesis of natural and unnatural piperidines
This work describes the platinum mediated ring opening isomerisation of 2,3-cyclopropanated piperidines, which results in either an endo or exocyclic olefin product. In the case where the beta-hydrogen is absent, a platinum-mediated Wagner-Meerwein type 1,2-alkyl shift reaction is observed. A sere...
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| Format: | Theses and Dissertations |
| Language: | English |
| Published: |
2017
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| Online Access: | http://hdl.handle.net/10356/72882 |
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| Institution: | Nanyang Technological University |
| Language: | English |