Electron transfer in nickel-catalyzed addition reactions of organozirconium compounds to unsaturated ketones

• Main Authors: Dayrit, Fabian M, Schwartz, Jeffrey
• Format: text
• Published: Archīum Ateneo 1981
• Subjects: Chemistry; Organic Chemistry
• Online Access: https://archium.ateneo.edu/chemistry-faculty-pubs/98; https://pubs.acs.org/doi/pdf/10.1021/ja00405a029
• Institution: Ateneo De Manila University

The species formed by reacting Ni (acac) 2 with 1 equiv of Dibah have been studied with regardto their ability to catalyze carbon-carbon bond-forming reactions involving organozirconium compounds. Catalytic activity for these species is noted upon mixing the nickeland aluminum reagents; activity fal...