Intermolecular insertion of dialkynylphosphanes into the M–C bond of cyclopalladated rings through activation by cyclometallated amines
A series of chiral ortho-platinated and -palladated complexes derived from N,N,α-trimethylbenzylamine has been prepared. The dialkynylphosphane PhP(C CMe)2 coordinated regiospecifically as a P M monodentate ligand to these cyclometallated units in the positions trans to the nitrogen donors of the...
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/101892 http://hdl.handle.net/10220/11162 |
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| Institution: | Nanyang Technological University |
| Language: | English |