Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate

Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate

The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbPh2)2Os3(CO)11 as the major product. In both cases, the intermediate from the oxi...

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書目詳細資料
Main Authors:	Li, Ying-Zhou, Ganguly, Rakesh, Leong, Weng Kee
其他作者:	School of Physical and Mathematical Sciences
格式:	Article
語言:	English
出版:	2014
主題:	DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
在線閱讀:	https://hdl.handle.net/10356/103225 http://hdl.handle.net/10220/24383
標簽:	添加標簽沒有標簽, 成為第一個標記此記錄!
機構:	Nanyang Technological University
語言:	English

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