A NHC-silyliumylidene cation for catalytic N‑formylation of amines using carbon dioxide
This study describes the use of a silicon(II) complex, namely, the NHC-silyliumylidene cation complex [(I ) SiH]I (1, I =:C{N(Me)C(Me)} ), to catalyze the chemoselective N-formylation of primary and secondary amines using CO and PhSiH under mild conditions to afford the corresponding formamides a...
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2021
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/149731 |
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| Institution: | Nanyang Technological University |
| Language: | English |