Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles

Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles

Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle.

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書目詳細資料
Main Authors:	Jiao, Zhiwei, Chee, Kwok Wei, Zhou, Jianrong Steve
其他作者:	School of Physical and Mathematical Sciences
格式:	Article
語言:	English
出版:	2017
主題:	Palladium catalysis Alkylnitrile
在線閱讀:	https://hdl.handle.net/10356/84965 http://hdl.handle.net/10220/43605
標簽:	添加標簽沒有標簽, 成為第一個標記此記錄!

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