Asymmetric hydroarsination reactions toward synthesis of alcohol functionalised C-chiral As–P ligands promoted by chiral cyclometallated complexes

• Main Authors: Cheow, Yuen Lin, Li, Yongxin, Leung, Pak-Hing, Pullarkat, Sumod A.
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2013
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: https://hdl.handle.net/10356/96150; http://hdl.handle.net/10220/17145
• Institution: Nanyang Technological University

The asymmetric hydroarsination reactions between diphenylarsine and 3-diphenylphosphanyl-but-3-en-1-ol and 2-diphenylphosphanyl-prop-2-en-1-ol have been achieved using the organopalladium complex containing ortho-metallated (R)-[1-(dimethylamino)ethylnaphthalene as the chiral reaction template in hi...