Palladacycle-catalyzed asymmetric hydrophosphination of enones for synthesis of C*- and P*-chiral tertiary phosphines
A highly reactive and stereoselective hydrophosphination of enones catalyzed by palladacycles for the synthesis of C*- and P*-chiral tertiary phosphines has been developed. When Ph2PH was employed as the hydrophosphinating reagent, a series of C*-chiral tertiary phosphines were synthesized (C*–P bon...
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Main Authors: | Pullarkat, Sumod A., Huang, Yinhua, Li, Yongxin, Leung, Pak-Hing |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/96850 http://hdl.handle.net/10220/11598 |
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Institution: | Nanyang Technological University |
Language: | English |
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