Copper(II) Triflate catalyzed amination of 1,3-dicarbonyl compounds
A method to prepare α,α-acyl amino acid derivatives efficiently by Cu(OTf)2+1,10-phenanthroline (1,10-phen)-catalyzed amination of 1,3-dicarbonyl compounds with PhI[DOUBLE BOND]NSO2Ar is described. The mechanism is thought to initially involve aziridination of the enolic form of the substrate, forme...
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Main Authors: | Ton, Thi My Uyen, Himawan, Fanny, Chang, Joyce Wei Wei, Chan, Philip Wai Hong |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2013
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Online Access: | https://hdl.handle.net/10356/99536 http://hdl.handle.net/10220/12901 |
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Institution: | Nanyang Technological University |
Language: | English |
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