N-heterocyclic carbene-catalyzed [3+4] cycloaddition and kinetic resolution of azomethine imines
The first N-heterocyclic carbene (NHC)-catalyzed [3+4] cycloaddition of azomethine imines and enals is disclosed. Oxidative catalytic remote activation of enals affords 1,4-dipolarophile intermediates that react with 1,3-dipolar azomethine imines to generate dinitrogen-fused seven-membered heterocyc...
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/104218 http://hdl.handle.net/10220/19444 |
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| Institution: | Nanyang Technological University |
| Language: | English |