A base-stabilized 2-silaallene
The reaction of [CH2(PPh2S)2] (1) with 2 equiv of MeLi in Et2O followed by addition of 0.5 equiv of SiCl4 afforded the base-stabilized 2-silaallene [(PPh2S)2CSiC(PPh2S)2] (2). It has been characterized by X-ray crystallography, NMR spectroscopy, and theoretical studies. The results show that compoun...
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| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/105686 http://hdl.handle.net/10220/16609 http://dx.doi.org/10.1021/om301175p |
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| Institution: | Nanyang Technological University |
| Language: | English |